Brad Pitt got a bit hot under the collar as he was teased about both of his famous wives on Zach Galifianakis' mock talk show.

The Fury actor appeared on Between Two Ferns and showed his sense of humour as he was subjected to some light-hearted ribbing about his ex-wife Jennifer Aniston and new wife Angelina Jolie in a comic sketch.

Brad squirmed when Zach, referring to Jen's show Friends, asked: "When you first saw Angelina was it one of those classic moments like when Ross first saw Rachel?"

He rolled his eyes and stared up at the sky as Zach played the Friends theme tune, but took it on the chin and said: "I like that song."

Zach teased the star about his relationship with wife Angelina during the Funny Or Die show, joking: "Is it hard to maintain a sun tan?"

When Brad asked why, Zach laughed: "Because you live in your wife's shadow."

Zach also quizzed him about losing his virginity, his charity work and asked him why he kept playing Nazi haters when it was weird for him to do so, because he looks like " Hitler's dream".

However, Brad had a prank of his own up his sleeve after the final question.

Zach asked: "Do you think people focus maybe too much on your looks and don't even, you know, realise that you're just a s****y actor?"

Instead of answering, Brad gave Zach a stern look - and spat his gum at him.